Yes This is possible. If you have 3 users created in your users tab, you can according shift licenses to which ever user you want like in my case I am using orchestrator 2020.
User1
I just disable the user to which the attended license is assigned and enable on the other user to which I have to assign it
User2
Like this
I don’t have an idea how this works in version 2022, but I assume it’sthe same