Firefox browser is not maximized while run from orchestrator whereas it is fine in studio and assistant

Try to Switch the project to Modern Experience and use the Chromium API in Input Mode.

Reference: Input Methods

Check the unattended robot resolution to match the robot machine resolution:

Check if the robot machine scale is set to 100%.

Check if the Firefox browser is updated to the latest version

Try to remove and reinstall the Firefox Browser extension.

Reference: Extension for Firefox

Also, you may take a look here: Automation Works in Attended Mode but Not in Unattended Mode