Yes the argument is passing correctly, as the flow is working properly when im using the assign activity just above the workflow. And there’s no spaces in the config file.
As per your comment above, can you please let us know whether you are facing issue only while assigning a default value ? If so, you will not able to do this as UiPath will not be able to find the value while initialising !
Please try to use within Assign activity and you shall get default value assigned to some other variables.
You cannot provide config path in the Default of the varaible in the initial stage itself it will throw object refrerence not set to an instance of object error since it cannot pass the value from the config file. instead of that you have to use assign as you already tried and one more method is you can use invoke work flow activity for opening any application there you can pass this WebsitePath value as argument.