Http request with URL segment, working in postman, but not in uipath

We are not supporting anymore the Studio version that you have. Reference: Out of support versions

We recommend these supported versions: 2021.10.8 and 2022.4.4 Reference: https://docs.uipath.com/overview-guide/docs/product-lifecycle

For your case, you may try to decrease or increase the UiPath.WebAPI.Activities package and retry.