Desktop application not getting opened in Picture-in-Picture

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Hello you have to first set up an Environment variables on your system so that the PIP window has enough time to open.

Your selector shows that Chrome window has not opened.

So,

First set the environmental variable and then run the application in PIP. Allow PIP window to fail. Take control of PIP Window and then open Chrome inside PIP and make sure the UiPath plugin has been enabled.

Now run the automation from studio.

It should work unless your selector is wrong.

Refer to this link to set the variable: